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Acyl Insertions and α-Reactivity（待翻譯）

Lecture 35

講座一：反應機制－能量及動力學級數和反應速率的關係
Lecture 2 Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities（待翻譯）
Lecture 3 Rate and Selectivity in Radical-Chain Reactions （待翻譯）
Lecture 4 Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions （待翻譯）
Lecture 5 Solvation, H-Bonding, and Ionophores（待翻譯）
Lecture 6 Brønsted Acidity and the Generality of Nucleophilic Substitution（待翻譯）
Lecture 7 Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile, Leaving Group（待翻譯）
Lecture 8 Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon（待翻譯）
Lecture 9 Pentavalent Carbon? E2, SN1, E1（待翻譯）
Lecture 10 Cation Intermediates – Alkenes: Formation, Addition, and Stability（待翻譯）
Lecture 11 Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes（待翻譯）
Lecture 12 Nucleophilic Participation During Electrophilic Addition to Alkenes: Halogen, Carbene, and Borane（待翻譯）
Lecture 13 Addition to Form Three-Membered Rings: Carbenoids and Epoxidation（待翻譯）
Lecture 14 Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis（待翻譯）
Lecture 15 Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization（待翻譯）
Lecture 16 Isoprenoids, Rubber, and Tuning Polymer Properties（待翻譯）
Lecture 17 Alkynes; Conjugation in Allylic Intermediates and Dienes（待翻譯）
Lecture 18 Linear and Cyclic Conjugation Theory; 4n+2 Aromaticity（待翻譯）
Lecture 19 Aromatic Transition States: Cycloaddition and Electrocyclic Reactions（待翻譯）
Lecture 20 Electronic and Vibrational Spectroscopy（待翻譯）
Lecture 21 Functional Groups and Fingerprints in IR Spectroscopy; Precession of Magnetic Nuclei（待翻譯）
Lecture 22 Medical MRI and Chemical NMR（待翻譯）
Lecture 23 Diamagnetic Anisotropy and Spin-Spin Splitting（待翻譯）
Lecture 24 Higher-Order Effects, Dynamics, and the NMR Time Scale（待翻譯）
Lecture 25 C-13 and 2D NMR – Electrophilic Aromatic Substitution（待翻譯）
Lecture 26 Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg（待翻譯）
Lecture 27 Triphenylmethyl and an Introduction to Carbonyl Chemistry（待翻譯）
Lecture 28 Mechanism and Equilibrium of Carbonyl Reactions（待翻譯）
Lecture 29 Imines and Enamines; Oxidation and Reduction（待翻譯）
Lecture 30 Oxidation States and Mechanisms（待翻譯）
Lecture 31 Periodate Cleavage, Retrosynthesis, and Green Chemistry（待翻譯）
Lecture 32 Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison（待翻譯）
Lecture 33 Green Chemistry; Acids and Acid Derivatives（待翻譯）
Lecture 34 Acids and Acid Derivatives（待翻譯）
Lecture 35 Acyl Insertions and α-Reactivity（待翻譯）
Lecture 36 α-Reactivity and Condensation Reactions（待翻譯）
Lecture 37 Proving the Configuration of Glucose and Synthesizing Two Unnatural Products（待翻譯）
Lecture 38 Review: Synthesis of Cortisone（待翻譯）

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Lecture 35 Acyl Insertions and α-Reactivity（待翻譯）

待翻譯

講座一：反應機制－能量及動力學級數和反應速率的關係
Lecture 2 Peculiar Rate Laws, Bond Dissociation Energies, and Relative Reactivities（待翻譯）
Lecture 3 Rate and Selectivity in Radical-Chain Reactions （待翻譯）
Lecture 4 Electronegativity, Bond Strength, Electrostatics, and Non-Bonded Interactions （待翻譯）
Lecture 5 Solvation, H-Bonding, and Ionophores（待翻譯）
Lecture 6 Brønsted Acidity and the Generality of Nucleophilic Substitution（待翻譯）
Lecture 7 Nucleophilic Substitution Tools - Stereochemistry, Rate Law, Substrate, Nucleophile, Leaving Group（待翻譯）
Lecture 8 Solvent, Leaving Group, Bridgehead Substitution, and Pentavalent Carbon（待翻譯）
Lecture 9 Pentavalent Carbon? E2, SN1, E1（待翻譯）
Lecture 10 Cation Intermediates – Alkenes: Formation, Addition, and Stability（待翻譯）
Lecture 11 Carbocations and the Mechanism of Electrophilic Addition to Alkenes and Alkynes（待翻譯）
Lecture 12 Nucleophilic Participation During Electrophilic Addition to Alkenes: Halogen, Carbene, and Borane（待翻譯）
Lecture 13 Addition to Form Three-Membered Rings: Carbenoids and Epoxidation（待翻譯）
Lecture 14 Epoxide Opening, Dipolar Cycloaddition, and Ozonolysis（待翻譯）
Lecture 15 Metals and Catalysis in Alkene Oxidation, Hydrogenation, Metathesis, and Polymerization（待翻譯）
Lecture 16 Isoprenoids, Rubber, and Tuning Polymer Properties（待翻譯）
Lecture 17 Alkynes; Conjugation in Allylic Intermediates and Dienes（待翻譯）
Lecture 18 Linear and Cyclic Conjugation Theory; 4n+2 Aromaticity（待翻譯）
Lecture 19 Aromatic Transition States: Cycloaddition and Electrocyclic Reactions（待翻譯）
Lecture 20 Electronic and Vibrational Spectroscopy（待翻譯）
Lecture 21 Functional Groups and Fingerprints in IR Spectroscopy; Precession of Magnetic Nuclei（待翻譯）
Lecture 22 Medical MRI and Chemical NMR（待翻譯）
Lecture 23 Diamagnetic Anisotropy and Spin-Spin Splitting（待翻譯）
Lecture 24 Higher-Order Effects, Dynamics, and the NMR Time Scale（待翻譯）
Lecture 25 C-13 and 2D NMR – Electrophilic Aromatic Substitution（待翻譯）
Lecture 26 Aromatic Substitution in Synthesis: Friedel-Crafts and Moses Gomberg（待翻譯）
Lecture 27 Triphenylmethyl and an Introduction to Carbonyl Chemistry（待翻譯）
Lecture 28 Mechanism and Equilibrium of Carbonyl Reactions（待翻譯）
Lecture 29 Imines and Enamines; Oxidation and Reduction（待翻譯）
Lecture 30 Oxidation States and Mechanisms（待翻譯）
Lecture 31 Periodate Cleavage, Retrosynthesis, and Green Chemistry（待翻譯）
Lecture 32 Measuring Bond Energies: Guest Lecture by Prof. G. Barney Ellison（待翻譯）
Lecture 33 Green Chemistry; Acids and Acid Derivatives（待翻譯）
Lecture 34 Acids and Acid Derivatives（待翻譯）
Lecture 35 Acyl Insertions and α-Reactivity（待翻譯）
Lecture 36 α-Reactivity and Condensation Reactions（待翻譯）
Lecture 37 Proving the Configuration of Glucose and Synthesizing Two Unnatural Products（待翻譯）
Lecture 38 Review: Synthesis of Cortisone（待翻譯）

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