研習資料
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這部份包括掃描原始文件的文檔和屏幕閱讀軟件不能使用,以#號標記的文檔。
以下的補充材料在課程中發表,以深化講座主題的深度,提供方程和常數值的參考。
活度系數方程 (PDF)#
總結活度在什麽時候使用什麽方程。註:用Davies方程來解答課堂問題。注意一個錯誤:Davies括弧擴展至包括“-bI”項。注意擴展的Debye-Hucke理論,我是指在考慮絡合作用時的真實離子强度(而不是溶液中完全溶解的離子)。真實的離子强度一般比假設完全溶解的離子强度要低的多。暫時只用後者(因爲還沒有學習絡合作用)。
酸度和鹼度常數 (PDF)
氣體常數 (PDF)#
描述各種氣體常數之間的微妙區別。沒有必要記住這些:這只是幫助閱讀不同文本的理解方程的差別。
Alpha方程 (PDF)
Deffeyes圖表 (PDF)
總碳酸鹽 與 總鹼度 與pH值
相律區分 (PDF)
相律的區分
痕量鐵Fe(III)的形成 (PDF)
This section contains documents created from scanned original files and other documents that could not be made accessible to screen reader software. A "#" symbol is used to denote such documents.
The following supplemental materials were presented through the course to add depth to some of the topics covered through lecture, as well as to provide references to equations and values of constants.
Practice Problems - Lecture 2 (PDF)#, Solutions (PDF)
Activity Coefficient Equations (PDF)#
A summary of when to use which equations for activity. Note: use Davies Eqn for class problems. Note an error: Davies brackets extend to include the "-bI" term. Note that for the extended Debye-Huckel, I refers to true ionic strength, where complexation is considered (rather than complete dissolution of the ions in solution). The true ionic strength is typically lower than the ionic strength that assumes complete dissociation. For now, you can use the latter (since you haven't learned about complexation yet).
Acidity and Basicity Constants (PDF)
Gas Constants (PDF)#
A description of the subtle differences between the various gas constants. You do not need to memorize these- this is just to help you understand the discrepancies in the equations as you go between different texts.
Alpha Equations (PDF)
Deffeyes Diagram (PDF)
TOT Carbonate vs. TOT Alk vs. pH
Phase Rule Clarifications (PDF)
Clarifications on the Phase Rule
Fe(III) Speciation (PDF)
