相關閱讀資料
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審定:無 |
課堂閱讀資料全出自主要課本,按章列出。
The readings in the class all come from the main textbook and are listed by chapter.
Morel, Francois M.和Janet G. Hering.《水化學原理與應用》Principles and Applications of Aquatic Chemistry,New York, NY: Wiley-Interscience, 1993. ISBN: 0471548960.
其他課堂指定的閱讀資料出自以下課本:
Other readings assigned in class came from the following texts:
Anderson, G. W.《自然系統的熱力學》Thermodynamics of Natural Systems,New York, NY: Wiley-Interscience, 2005. ISBN: 0521847729.
Anderson, G. W. Thermodynamics of Natural Systems. New York, NY: Wiley-Interscience, 2005. ISBN: 0521847729.
Stumm, Werner和James J. Morgan.《水化學》Aquatic Chemistry,New York, NY: Wiley-Interscience, 1996. ISBN: 0471511854. 簡體譯本《水化學—天然水體化學平衡導論》湯鴻霄等譯,北京:科學出版社,1987年(較早版本的譯本)
Stumm, Werner, and James J. Morgan. Aquatic Chemistry. New York, NY: Wiley-Interscience, 1996. ISBN: 0471511854.
| 課 | 課程單元 | 閱讀資料 | |
|---|---|---|---|
| I. Review of Thermodynamics, and Setting Up and Solving Equilibrium Problems | |||
| 1 | 介紹,回顧熱力學定律 Introduction, Review of Laws of Thermodynamics 介紹表列法 Introduction to Tableau Method |
第一章 Chapter 1 |
|
| 2 | 吉布斯自由能,化學勢等常量 Gibbs Free Energy, Chemical Potential, eq. Constants 設定均衡問題:表列法 Setting Up Equilibrium Problems - Tableau Method |
第一、二章 Chapters 1 and 2 |
|
| 3-4 | 以近似法解題:Log C與pH 圖表 Solving Problems by Approximation - Log C vs. pH Diagrams |
第一、二章 Chapters 1 and 2 |
|
| 5 | 溫度,壓力及離子强度對均衡的影響 Temperature, Pressure, and Ionic Strength Effects on Equilibrium |
第二章 Chapter 2 |
|
| 6 | 水的特性,溶質間的反應,活度系數 Properties of Water, Interactions Among Solutes, Activity Coefficients |
Chapter 2 | |
| 7 | 活度系數和Debye-Huckel理論 Activity Coefficients and Debye-Huckel Theory |
第二章 Chapter 2 |
|
| II. Acid-base Chemistry of Natural Waters | |||
| 8-9 | 碳酸鹽系統和鹼度 The Carbonate System and Alkalinity |
第四章 Chapter 4 |
|
| 10 | 鹼度的用處 Uses of Alkalinity |
第四章 Chapter 4 |
|
| 11 | 鹼度概念的局限性 Limitations of Alkalinity Concept |
第四章 Chapter 4 |
|
| 12 | 緩衝能力 Buffer Capacity |
第四章 Chapter 4 |
|
| 13 | 課堂討論:期中考試(課後完成) Class Discussion - Mid-term (Take-home) |
||
| III. Dissolution and Precipitation | |||
| 14 | 礦物的可溶性 Mineral Solubility |
第六章 Chapter 6 |
|
| 15 | 穩定圖 Stability Diagrams |
第六章 Chapter 6 |
|
| 16 | 化學侵蝕和自然水組成 Chemical Weathering and Natural Water Composition |
第六章> Chapter 6 |
|
| IV. Complexation | |||
| 17 | 介紹絡合作用 Introduction to Complexation |
第五章 Chapter 5 |
|
| 18 | 痕量金屬:有機物的絡合作用 Trace Metals - Inorganic Complexation |
第五章 Chapter 5 |
|
| V. Redox Chemistry | |||
| 19 | 介紹氧化還原化學(不用表列法) Introduction to Redox Chemistry (Don't use Tableaux) |
第七章 Chapter 7 |
|
| 20 | 氧化還原化學平衡的計算 Equilibrium Calculations with Redox Reactions |
第七章 Chapter 7 |
|
| 21 | 氧化還原勢(pe)作爲系統變數 Redox Potential (pe) as a System Variable |
第七章 Chapter 7 |
|
| 22 | pe-pH 圖 pe-pH 圖 pe-pH Diagrams |
第七章 Chapter 7 |
|
| 23 | 痕量金屬:有機物的絡合作用 Trace Metals - Organic Complexation |
第七章 Chapter 6 |
|
| 24 | 絡合作用和沉澱對氧化還原均衡的影響 Effects of Complexation and Precipitation on Redox Equilibria |
第七章 Chapter 7 |
|
| VI. Chemical Kinetics | |||
| 25 | 均勻系統的氧化動力學 Oxidation Kinetics in Homogeneous Systems |
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| 26 | 均勻系統 Heterogeneous Systems 酶催化 Enzyme Catalysis |
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