| L1 |
簡介Introduction
統計力學的目的Purpose of Stat Mech
機率Probability |
指定#1練習題集Problem set #1 out |
| L2 |
機率(續)Probability (cont.) |
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| L3 |
平衡狀態Equilibrium States |
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| L4 |
平衡狀態Equilibrium States
擴散之晶格模型Lattice Model for Diffusion
橡膠彈性學Rubber Elasticity
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交#1練習題集解答Problem set #1 due
指定#2練習題集Problem set #2 out |
| L5 |
簡介熱力學守恆定律(第一定律，量化與第二定律)Introduction to Conservation Laws (1st Law, Quantization, 2nd Law) |
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| L6 |
外延性質：波茲曼定律與熵(entropy)Boltzmann's Law and Entropy as an Extensive Property
熵增加的定律Law of Increased Entropy |
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| L7 |
波茲曼定律與外延性質熵(entropy)More Boltzmann's Law
分配函數Partition Functions |
交#2練習題集解答Problem set #2 due |
| L8 |
模擬計算Simulations
聚合酵素鏈鎖反應PCR |
|
| E1 |
隨堂測驗一Quiz I |
指定#3練習題集Problem set #3 out |
| L9 |
熱力學系統Thermodynamic Systems
內含與外延性質Intensive/Extensive Properties
能量與熵(Entropy)的基本方程式 Fundamental Equations for Energy and Entropy
熱力學驅動力之定義(第一部分)Definitions of Thermodynamic Driving Forces (Part 1)
熱力學作用力Thermodynamic Forces
Homogeneous Functions
平衡，溫度與壓力的定義Definition of Equilibrium, Temperature, Pressure
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| L10 |
簡介化學位能Introduction to Chemical Potential
熱循環Thermo Cycles
熱，功與能量之間關係的第一定律First Law Relations between Heat, Work, Energy
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| L11 |
可逆與不可逆程序Reversible and Irreversible Processes |
交#3練習題集解答Problem set #3 due
指定#4練習題集Problem set #4 out |
| L12 |
簡介自由能Introduction to Free Energy
赫姆荷茲自由能Helmholtz Free energy |
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| L13 |
焓Enthalpy
吉布斯自由能Gibbs Free Energy |
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| L14 |
基本方程式與其自然變數Fundamental Equations and their Natural Variables
熱容Heat Capacities
平衡溫度 Equilibrium Temperature |
交#4練習題集解答Problem set #4 due
指定#5練習題集Problem set #5 out |
| L15 |
熱力學循環Thermodynamic Cycles
卡若循環與不等性質Carnot Cycle and Inequality
熱引擎Heat Engines
路徑相依性Path Dependence |
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| L16 |
莫爾偏微性質Partial Molar Properties |
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| L17 |
部莫爾偏微性質IIPartial Molar Properties II |
交#5練習題集解答Problem set #5 due |
| L18 |
電腦模擬Simulations
蒙地卡羅法Monte Carlo |
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| E2 |
隨堂測驗二Quiz II |
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| L19 |
波茲曼分布定律Boltzmann Distribution Law |
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| L20 |
分配函數Partition Functions |
L20課程前五天指定#6練習題集Problem set #6 out 5 days before L20 |
| L21 |
從分配函數預測熱力學性質Prediction of Thermodynamic Properties from Partition Functions
系集Ensembles |
交#6練習題集解答Problem set #6 due
指定#7練習題集Problem set #7 out |
| L22 |
量子分配函數Quantum Partition Function |
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| L23 |
均分原理Equipartition |
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| L24 |
均分原理 (續)Equipartition (cont.) |
交#7練習題集解答Problem set #7 due
指定#8練習題集Problem set #8 out |
| L25 |
化學平衡Chemical Equlibria
列沙特勒原理 (Ex. 8, 蛋白質的應力變性)Le Chatelier's Principle (Ex. 8, Pressure Denaturation of Proteins)
凡特何夫(van’t Hoff)原理van't Hoff |
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| L26 |
固-液-氣平衡Solid-liquid-gas Equilibrium |
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| L27 |
溶液與混合物Solutions and Mixtures
高分子Polymers |
交#8練習題集解答Problem set #8 due |
| L28 |
溶解現象:滲透壓Solvation: Osmotic Pressure
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L28課程前2天指定#9練習題集Problem set #9 out two days before L28 |
| L29 |
溶解現象:蛋白質/巨分子在介面的吸附現象Solvation: Protein/Macromolecule Adsorption at Interfaces |
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| L30 |
高分子鏈Polymer Chain |
交#9練習題集解答Problem set #9 due |
| E3 |
隨堂測驗三Quiz III |
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| L31 |
高分子鏈 IIPolymer Chain II |
指定#10練習題集Problem set #10 out |
| L32 |
高分子鏈 IIIPolymer Chain III |
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| L33 |
協同性Cooperativity |
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| L34 |
協同性 (續)Cooperativity (cont.) |
交#10練習題集解答Problem set #10 due |
| L35 |
蛋白質摺疊現象Protein Folding |
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| L36 |
回顧Review |
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