5.04 2004秋季课程：无机化学原理II(Principles of Inorganic Chemistry II, Fall 2004)
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一氧化碳（CO）是一个π键受体。CO和金属结合的键有两部份：σ键和π反馈键。（麻省理工学院开放式课程提供插图）
Carbon monoxide (CO) is a π accepting ligand. The bonding of CO to a metal has two components: σ bonding and π backbonding. (Illustration by MIT OCW.)
课程重点
课程描述
这门课程系统地阐述群论在化学中的应用，着重于这门学科及其应用于无机化合物的物理方法之常规进展。并对分子的电子结构做进一步研究。在这背景下，陈述过渡金属配合物的光学、振动和磁学性质，以及通过适当的光谱方法探讨这些性质。
This course provides a systematic presentation of the chemical applications of group theory with emphasis on the formal development of the subject and its applications to the physical methods of inorganic chemical compounds. The electronic structure of molecules will be developed. Against this backdrop, the optical, vibrational, and magnetic properties of transition metal complexes are presented and their investigation by the appropriate spectroscopy is described.
This course provides a systematic presentation of the chemical applications of group theory with emphasis on the formal development of the subject and its applications to the physical methods of inorganic chemical compounds. The electronic structure of molecules will be developed. Against this backdrop, the optical, vibrational, and magnetic properties of transition metal complexes are presented and their investigation by the appropriate spectroscopy is described.
